SELECTIVE FRAGMENTATION OF NITROUS-OXIDE BY SITE-SPECIFIC N-(1S) EXCITATION USING SOFT-X-RAY SYNCHROTRON RADIATION

被引：32

作者：

HABENICHT, W ^{[1
]}

BAITER, H ^{[1
]}

MULLERDETHLEFS, K ^{[1
]}

SCHLAG, EW ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST PHYS & THEORET CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY

来源：

PHYSICA SCRIPTA | 1990年 / 41卷 / 06期

关键词：

D O I：

10.1088/0031-8949/41/6/020

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We observe bond-selective fragmentation of the nitrous oxide molecule upon site-specific 1s excitation at either the terminal or the central nitrogen atom. Our results can be interpreted as a chemical "memory effect" where the fragmentation process memorizes the inital site of energy deposition. We empty a new "Zero Kinetic Energy Photoelectron"-photoion coincidence technique using monochromatized x-ray synchrotron radiation from BESSY. © 1990 IOP Publishing Ltd.

引用

页码：814 / 818

页数：5

共 15 条

[1] K-SHELL PHOTOABSORPTION SPECTRA OF N2 AND N2O USING SYNCHROTRON RADIATION [J].

BIANCONI, A ;

PETERSEN, H ;

BROWN, FC ;

BACHRACH, RZ .

PHYSICAL REVIEW A, 1978, 17 (06) :1907-1911

[2] MULTI-PHOTON MASS-SPECTROMETRY OF METASTABLES - DIRECT OBSERVATION OF DECAY IN A HIGH-RESOLUTION TIME-OF-FLIGHT INSTRUMENT [J].

BOESL, U ;

NEUSSER, HJ ;

WEINKAUF, R ;

SCHLAG, EW .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (25) :4857-4863

[3] EXPERIMENTAL AND THEORETICAL-STUDY OF AUGER SPECTRUM OF NITROUS-OXIDE [J].

CONNOR, JA ;

HILLIER, IH ;

KENDRICK, J ;

BARBER, M ;

BARRIE, A .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (08) :3325-3329

[4]

ERNSTBERGER B, UNPUB COMPUTATIONS

[5] RECENT PROGRESS IN ESCA STUDIES OF GASES [J].

GELIUS, U .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1974, 5 (NOV-D) :985-1057

[6]

HABENICHT W, 1987, J PHYS C SOLID STATE, V9, P741

[7]

HABENICHT W, 1990, J ELECTRON SPECT APR

[8]

HABENICHT W, UNPUB REV SCI INSTR

[9] IONIC FRAGMENTATION OF INNER SHELL EXCITED-STATES OF CO2 AND N2O [J].

HITCHCOCK, AP ;

BRION, CE ;

VANDERWIEL, MJ .

CHEMICAL PHYSICS LETTERS, 1979, 66 (02) :213-217

[10] THE CORE HOLE DECAY OF N2O FOLLOWING CORE TO BOUND-STATE EXCITATIONS [J].

LARKINS, FP ;

EBERHARDT, W ;

LYO, IW ;

MURPHY, R ;

PLUMMER, EW .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (05) :2948-2955

← 1 2 →