HYDROSILYLATION OF CARBONYL-COMPOUNDS CATALYZED BY SOLID ACIDS AND BASES

被引：24

作者：

IZUMI, Y

NANAMI, H

HIGUCHI, K

ONAKA, M

机构：

[1] Department of Applied Chemistry, School of Engineering, Nagoya University, Chikusa-ku, Nagoya, 464, Furo-cho

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 36期

关键词：

HYDROSILYLATION; MONTMORILLONITE; HYDROXYAPATITE; CALCIUM OXIDE;

D O I：

10.1016/S0040-4039(00)92296-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrosilylation of carbonyl compounds with hydrosilane is efficiently catalyzed by inorganic solid acids and bases such as Fe3+ ion-exchanged montmorillonite and hydroxyapatite (Ca10(PO4)6(OH)2) at reaction temperatures between 25 and 90-degrees-C. Enones are also selectively hydrosilylated in the presence of hydroxyapatite to afford the corresponding 1,2-addition products in high yields.

引用

页码：4741 / 4744

页数：4

共 9 条

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[9] [No title captured]

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