HIGHLY SELECTIVE ONE-STEP FORMATION OF METHYL ISOBUTYL KETONE FROM ACETONE WITH A MAGNESIA SUPPORTED NICKEL-CATALYST

被引：64

作者：

GANDIA, LM ^{[1
]}

MONTES, M ^{[1
]}

机构：

[1] UNIV BASQUE COUNTRY, FAC QUIM,DEPT QUIM APLICADA,INGN QUIM GRP, APDO 1072, E-20080 SAN SEBASTIAN, SPAIN

来源：

APPLIED CATALYSIS A-GENERAL | 1993年 / 101卷 / 01期

关键词：

ACETONE; METHYL ISOBUTYL KETONE; NICKEL MAGNESIA;

D O I：

10.1016/0926-860X(93)80132-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new catalyst for the production of methyl isobutyl ketone (MIBK) from acetone and hydrogen in one step at atmospheric pressure has been prepared. The catalyst was obtained by impregnation of MgO with an aqueous solution of nickel nitrate, dried, calcined in air and reduced in hydrogen. This catalyst showed a high selectivity to MIBK, reaching in some experiments between 60 and 80%. A loss of activity with time on stream, probably due to coke deposition was also found. An increase in reduction temperature from 300 to 500-degrees-C gives a decrease in MIBK selectivity that is due to an increase in the yield of 2-propanol.

引用

页码：L1 / L6

页数：6

共 11 条

[1] MAGNESIA-SUPPORTED NICKEL-CATALYSTS .1. FACTORS AFFECTING THE STRUCTURE AND MORPHOLOGICAL PROPERTIES [J].