PHOSPHONITRILIC COMPOUNDS .8. REACTION OF O-AMINOPHENOL WITH PHOSPHAZENES

被引：37

作者：

ALLCOCK, HR

KUGEL, RL

机构：

[1] Department of Chemistry, Pennsylvania State University, University Park

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 20期

关键词：

D O I：

10.1021/ja01048a009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

o-Aminophenol reacts with a number of halo- and organophosphazenes in boiling xylene to yield bis-(o-phenyleneoxyamino)-2-aminophenoxyphosphorane (III) and ammonium halide or ammonia. This ring cleavage reaction occurs with (NPCI2)3, (NPCI2)4, (NPCI2)15.000, (NPBr2)3, (NPF2)3, and with certain organocyclotriphospha-zenes which contain a five-membered cyclic side unit attached to phosphorus. No reaction was observed with [NP-(OC6H5)2]3, [NP(OC6H4NO2)2]3, [NP(NHC6H5)2]3, or [NP(O2C12H8)]3. The structural proof for III is described and the complex reaction mechanism is discussed. © 1969, American Chemical Society. All rights reserved.

引用

页码：5452 / &

共 26 条

[1] PHOSPHONITRILIC COMPOUNDS .7. HIGH MOLECULAR WEIGHT POLY(DIAMINOPHOSPHAZENES)
ALLCOCK, HR
KUGEL, RL
[J]. INORGANIC CHEMISTRY, 1966, 5 (10) : 1716 - &
[2] PHOSPHONITRILIC COMPOUNDS .6. HIGH MOLECULAR WEIGHT POLY(ALKOXY- AND ARYLOXPHOSPHAZENES)
ALLCOCK, HR
KUGEL, RL
VALAN, KJ
[J]. INORGANIC CHEMISTRY, 1966, 5 (10) : 1709 - &
[3] PHOSPHONITRILIC COMPOUNDS .I. MECHANISM OF PHOSPHONITRILIC CHLORIDE POLYMERIZATION CAPACITANCE CONDUCTANCE + ELECTRON-SPIN RESONANCE STUDIES
ALLCOCK, HR
BEST, RJ
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1964, 42 (02): : 447 - &
[4] DEGRADATION OF HALOGENOPHOSPHAZENES TO A NEW PHOSPHORANE SYSTEM
ALLCOCK, HR
KUGEL, RL
[J]. CHEMICAL COMMUNICATIONS, 1968, (24) : 1606 - &
[5] PHOSPHONITRILIC COMPOUNDS .2. REACTIONS OF PHOSPHONITRILIC CHLORIDES WITH CATECHOL + TRIETHYLAMINE
ALLCOCK, HR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (13) : 2591 - &
[6] PHOSPHONITRILIC COMPOUNDS .V. CYCLIZED PRODUCTS FROM REACTIONS OF HEXACHLOROCYCLOTRIPHOSPHAZENE (PHOSPHONITRILIC CHLORIDE TRIMER) WITH AROMATIC DIHYDROXY DITHIOL AND DIAMINO COMPOUNDS
ALLCOCK, HR
KUGEL, RL
[J]. INORGANIC CHEMISTRY, 1966, 5 (06) : 1016 - &
[7] ALLCOCK HR, 1967, HETEROATOM RING SYST, pCH7
[8] ALLCOCK HR, UNPUBLISHED WORK
[9] ZUR KENNTNIS DER PHOSPHORNITRILCHLORIDE .2. REAKTIONEN VON NUCLEOPHILEN REAGENTIEN MIT TRIMEREM PHOSPHORNITRILCHLORID
BECKEGOEHRING, M
JOHN, K
FLUCK, E
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1959, 302 (1-2): : 103 - 120
[10] UBER PHOSPHORNITRIL-VERBINDUNGEN .4. DIE STRUKTUR UND UBER AMIDE DES TRIMEREN
BODE, H
BUTOW, K
LIENAU, G
[J]. CHEMISCHE BERICHTE-RECUEIL, 1948, 81 (06): : 547 - 552

← 1 2 3 →