CALCULATED RADIATIONLESS TRANSITION RATES FOR BENZENE AND DEUTEROBENZENE

Radiationless rates have been calculated for the 3B 1u→1A1g transitions of benzene and perdeuterobenzene as well as for the 1B1u→ 1A1g transition of benzene. The rates were calculated using a model that considers the radiationless transition as a tunneling process between two multidimensional potential surfaces and assuming both harmonic and anharmonic vibrational potentials. The importance of anharmonicity for the radiationless transition rate provides a possible explanation of environmental effects on these rates. Whenever possible, experimental parameters were used in the calculation. To this end we have obtained experimental values for the anharmonicities of the carbon-carbon and carbon-hydrogen vibrations and the size of the lowest triplet state of benzene.