PSEUDO-POLAROGRAMS - APPLIED POTENTIAL ANODIC STRIPPING PEAK CURRENT RELATIONSHIPS

被引：43

作者：

SHUMAN, MS

CROMER, JL

机构：

[1] Department of Environmental Sciences and Engineering, School of Public Health, University of North Carolina, Chapel Hill

来源：

ANALYTICAL CHEMISTRY | 1979年 / 51卷 / 09期

关键词：

D O I：

10.1021/ac50045a043

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Applied potential-anodic stripping peak current relationships for reversible and nonreversible electrochemical reactions were generated using diffusion layer theory. Theoretical correlations between pseudopolarogram half-wave potentials and pre-electrolysis time, heterogeneous rate constants and electrode radius were obtained and relationships between applied potential and log [(i,-i)/l] for both reversible and nonreversible reactions were calculated. The anodic stripping voltammetry of TI(I) agreed with the theory for reversible reactions. © 1979, American Chemical Society. All rights reserved.

引用

页码：1546 / 1550

页数：5

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