Electron spin resonance measurements of dibenzenechromium cation

被引：87

作者：

Prins, R. ^{[1
]}

Reinders, F. J. ^{[1
]}

机构：

[1] Amsterdam Shell Res BV, Koninklijke Shell Lab, Amsterdam, Netherlands

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 01期

关键词：

D O I：

10.1016/0009-2614(69)80016-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

ESR spectra of liquid and solid solutions of Cr(C6H6)(2) I have been measured. Even in solid solution the spectra a show a well resolved proton hyperfine structure which is explained by rotation of the Cr(C6H6)(2)(+) cation around its main axis. An analysis of the Cr-53 hyperfine coupling constants indicates that the unpaired electron is in the a(1g) (3d(z2)) orbital. The experimental results agree fairly well with the results of an extended Huckel MO calculation.

引用

页码：45 / 48

页数：4

共 22 条

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