ELECTROCHEMICAL SYNTHESIS OF SOME PH3SNMCL ADDUCTS (M=ZN, CD, HG)

被引：11

作者：

HABEEB, JJ ^{[1
]}

OSMAN, A ^{[1
]}

TUCK, DG ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

INORGANICA CHIMICA ACTA | 1979年 / 35卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)93425-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrochemical oxidation of Zn, Cd or Hg (= M) in a non-aqueous solution of Ph3SnCl yields the metal-metal bonded insertion product Ph3SnMCl which can be easily isolated as an adduct present in the solvent phase. The mechanism of this direct electrochemical synthesis is discussed. The far infrared spectra (500-50 cm-1) of these compounds are also reported. © 1979.

引用

页码：105 / 108

页数：4

共 12 条

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[4] ORGANOMETALLIC ELECTROCHEMISTRY .7. NUCLEOPHILICITIES OF METALLIC AND METALLOIDAL ANIONS DERIVED FROM METALS OF GROUPS 4,5,6,7, AND 8
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HABEEB, JJ
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 146 (03) : 213 - 219
[7] ELECTROCHEMICAL PREPARATION OF SOME ORGANOTIN COMPOUNDS
HABEEB, JJ
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 134 (03) : 363 - 379
[8] HABEEB JJ, UNPUBLISHED
[9] HABEEB JJ, 1976, CHEM COMMUN, P379
[10] TOMBE FJA, 1972, J ORGANOMET CHEM, V43, P323

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