CYCLOMETALLATED COMPOUNDS .8. DOUBLE CYCLOPALLADATION OF DIACETYLBENZENE DIOXIMES AND 1,5-BIS(DIMETHYLAMINO)NAPHTHALENE

被引：48

作者：

PHILLIPS, IG ^{[1
]}

STEEL, PJ ^{[1
]}

机构：

[1] UNIV CANTERBURY, DEPT CHEM, CHRISTCHURCH 1, NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80010-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dioximes of 1,3- and 1,4-diacetylbenzene readily undergo regioselective double cyclopalladation on reaction with lithium tetrachloropalladate. 1,5-Bis(dimethylamino)naphthalene has been singly and doubly cyclopalladated; attempts to prepare heterodicyclometallated derivatives of this ligand were not successful. An X-ray crystal structure of the singly cyclometallated Pd(acac) complex of 1,5-bis(dimethylamino)naphthalene has been determined.

引用

页码：247 / 255

页数：9

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