GENERATION OF ALKYLIDENECARBENES BY THE ALKENYLATION OF CARBONYL-COMPOUNDS WITH LITHIOTRIMETHYLSILYLDIAZOMETHANE

被引：116

作者：

OHIRA, S

OKAI, K

MORITANI, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 09期

关键词：

D O I：

10.1039/c39920000721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of carbonyl compounds and lithiotrimethylsilyldiazomethane, which generate alkylidenecarbenes, gives a terminal acetylene from an aldehyde and cyclopentene derivatives from ketones.

引用

页码：721 / 722

页数：2

共 14 条

[1] SIMPLE PROCEDURE FOR ELABORATION OF CARBONYL-COMPOUNDS INTO HOMOLOGOUS ALKYNES
COLVIN, EW
HAMILL, BJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (08): : 869 - 874
[2] REACTIONS OF ALKYLIDENECARBENES DERIVED FROM N,N-DISUBSTITUTED-2-OXOPROPANAMIDES - THE FORMATION OF 3-PYRROL-2-ONES AND 2-BUTYNAMIDES
GILBERT, JC
BLACKBURN, BK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (19) : 3656 - 3663
[3] INSERTION OF AN ALKYLIDENECARBENE INTO THE SILICON-HYDROGEN BOND - ISOTOPE EFFECT FOR THE REACTION
GILBERT, JC
GIAMALVA, DH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (14) : 2586 - 2587
[4] INTRAMOLECULAR CARBON-HYDROGEN INSERTIONS OF ALKYLIDENECARBENES .1. SELECTIVITY
GILBERT, JC
GIAMALVA, DH
WEERASOORIYA, U
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (26) : 5251 - 5256
[5] GENERATION OF ALDEHYDIC ENOL ETHERS AND ENAMINES BY OLEFINATION OF KETONES
GILBERT, JC
WEERASOORIYA, U
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (04) : 448 - 453
[6] A NOVEL PREPARATION OF CYCLOHEPTA[B]PYRROL-2-ONES
GILBERT, JC
BLACKBURN, BK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (21) : 4087 - 4089
[7] GILBERT JC, 1985, J ORG CHEM, P2557
[8] OCHIAI M, 1991, J AM CHEM SOC, V113, P3134
[9] C-H INSERTION METHOD FOR THE CHIRAL TERTIARY ALCOHOL - FORMAL SYNTHESIS OF (-)-FRONTALIN
OHIRA, S
ISHI, S
SHINOHARA, K
NOZAKI, H
[J]. TETRAHEDRON LETTERS, 1990, 31 (07) : 1039 - 1040
[10] METHANOLYSIS OF DIMETHYL (1-DIAZO-2-OXOPROPYL)PHOSPHONATE - GENERATION OF DIMETHYL (DIAZOMETHYL)PHOSPHONATE AND REACTION WITH CARBONYL-COMPOUNDS
OHIRA, S
[J]. SYNTHETIC COMMUNICATIONS, 1989, 19 (3-4) : 561 - 564

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