The Inherent Instability of 1,3-Dioxan and the Conformation of 1,3,7,9-Tetraoxacyclododecane

被引：15

作者：

Borgen, Gerd ^{[1
]}

Dale, Johannes ^{[1
]}

机构：

[1] Univ Oslo, Kjemisk Inst, N-3 Oslo, Norway

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1974年 / 12期

关键词：

D O I：

10.1039/c39740000484

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conformation of 1,3,7,9-tetraoxacyclododecane, formed by dimerization of 1,3-dioxan, is shown by n.m.r. spectroscopy to be 'square,' with both 1,3-dioxa-groupings across corners, and to possess a very high conformational barrier (11 kcal/mol).

引用

页码：484 / U22

页数：2

共 21 条

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