WATER-SOLUBLE PHTHALOCYANINES CONTAINING AZA-CROWN ETHER SUBSTITUENTS

被引：101

作者：

MUSLUOGLU, E

AHSEN, V

GUL, A

BEKAROGLU, O

机构：

[1] TUBITAK MARMARA RES CTR,DEPT CHEM,POB 21,GEBZE 41470,TURKEY

[2] TECH UNIV ISTANBUL,DEPT CHEM,ISTANBUL,TURKEY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 11期

关键词：

AZA-CROWN ETHERS; PHTHALOCYANINES; AMPHIPHILIC; QUATERNARY LUTETIUM BIS(PHTHALOCYANINATES); QUATERNERIZATION OF ACETYL AMINES; LUTETIUM COMPLEXES;

D O I：

10.1002/cber.19911241123

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A straightforward and generalizable synthesis of metal-free and metal (Ni, Pb, Lu) derivatives of symmetrically tetrasubstituted phthalocyanines derived from 15,16-dibromo- or -dicyano-2,3,6,7,8,9,11,12-octahydro-5H-benzo[e][1,4,7,13]tetroxazacyclopentadecine (1) is described. Quaternarization of the N-acetyl derivatives 7 in a chloroform/dimethyl sulfate mixture gives phthalocyanines 9 soluble in the pH range of 1 - 13. The electronic spectra of the phthalocyanines in buffered solutions (pH 4, 7, and 10) are examined. Furthermore, the electronic spectra of lutetium bis(phthalocyaninate) 9 d in water and in DMSO are compared for the first time.

引用

页码：2531 / 2536

页数：6

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