THE PREPARATION OF GIBBERELLIN HAPTEN PROTEIN CONJUGATES .2. CONJUGATES AND GIBBERELLIN AFFINITY PROBES FORMED VIA THE ADDITION OF ALPHA,OMEGA-DITHIOLS TO C-16-ENES

被引：7

作者：

BEALE, MH

机构：

[1] Department of Agricultural Sciences, University of Bristol, AFRC Institute of Arable Crops Research, Bristol, BS18

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 10期

关键词：

D O I：

10.1039/p19910002559

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The free radical addition of alpha,omega-dithiols to a range of gibberellins is described. The resulting 17-mercaptoalkylthiogibberellins were easily coupled, via reaction with maleic anhydride, to protein carriers for use of as antigens in the preparation of anti-gibberellin antibodies. These derivatives were also allowed to react with a number of electrophilic reagents to prepare fluorescent, biotinylated and photoreactive gibberellin probes, as well as immobilised gibberellins.

引用

页码：2559 / 2563

页数：5

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