ELECTROGENERATED ZINC AS THE CATALYST IN THE ALLYLATION OF CARBONYL-COMPOUNDS DIRECT SYNTHESIS OF ALPHA-METHYLENE-GAMMA-LACTONES

被引：31

作者：

ROLLIN, Y ^{[1
]}

DERIEN, S ^{[1
]}

DUNACH, E ^{[1
]}

GEBEHENNE, C ^{[1
]}

PERICHON, J ^{[1
]}

机构：

[1] UNIV NICE SOPHIA ANTIPOLIS,CHIM MOLEC LAB,CNRS,F-06108 NICE 2,FRANCE

来源：

TETRAHEDRON | 1993年 / 49卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(01)87246-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electroreduction of a catalytic amount of ZnBr2 in acetonitrile provided a active Zn*, able to catalyze the reductive coupling of allyl bromides and chlorides with carbonyl compounds with high regioselectivity. Substituted alpha-methylene gamma-lactones were obtained from functionalized allyl derivatives.

引用

页码：7723 / 7732

页数：10

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