PHOSPHINERHODIUM COMPLEXES AS HOMOGENEOUS CATALYSTS .10. HOMOGENEOUS HYDROGENATION OF KETONES USING PHOSPHINERHODIUM CATALYSTS MODIFIED WITH TRIETHYLAMINE

被引：31

作者：

HEIL, B

TOROS, S

BAKOS, J

MARKO, L

机构：

[1] Department of Organic Chemistry, University of Chemical Engineering

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 175卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)84544-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Triethylamine significantly increases the catalytic activity in ketone hydrogenation of rhodium complexes containing aromatic phosphines. If chiral phosphines are used, optical yields depend on the amount of triethylamine added, suggesting that several catalytically active species are involved. © 1979.

引用

页码：229 / 232

页数：4

共 16 条

[1] ASYMMETRIC HYDROGENATION WITH NEW CHIRAL FUNCTIONALIZED BISPHOSPHINE-RHODIUM COMPLEXES
ACHIWA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (25) : 8265 - 8266
[2] CULLEN WR, 1978, TETRAHEDRON LETT, P1635
[3] FIORINI M, 1975, J MOL CATAL, V1, P451
[4] ASYMMETRIC SYNTHESIS - PRODUCTION OF OPTICALLY-ACTIVE AMINO-ACIDS BY CATALYTIC-HYDROGENATION
FRYZUK, MD
BOSNICH, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (19) : 6262 - 6267
[5] HAYASHI T, 1977, TETRAHEDRON LETT, P295
[6] HAYASHI T, 1976, TETRAHEDRON LETT, P4351
[7] HOMOGENEOUS CATALYTICAL ASYMMETRICAL HYDROGENATION OF KETONES
HEIL, B
TOROS, S
VASTAG, S
MARKO, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 94 (03) : C47 - C48
[8] ASYMMETRIC CATALYTIC REDUCTION WITH TRANSITION-METAL COMPLEXES .1. CATALYTIC SYSTEM OF RHODIUM(I) WITH (-)-2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE - NEW CHIRAL DIPHOSPHINE
KAGAN, HB
DANG, TP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (18) : 6429 - &
[9] KING RR, J ORG CHEM
[10] SYNTHESIS OF METHYLDIPHENYLPHOSPHINE AND NEOMETHYLDIPHENYLPHOSPHINE - EPIMERIC, CHIRAL, TERTIARY PHOSPHINE LIGANDS FOR ASYMMETRIC SYNTHESIS
MORRISON, JD
MASLER, WF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (02) : 270 - 272

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