1ST GENERAL-SYNTHESIS OF MONOSILYL ACETALS - TRIMETHYLSILYL TRAPPING OF THE INTERMEDIATE IN DIBALH REDUCTION OF CARBOXYLIC-ACID ESTERS USING TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE

被引：30

作者：

KIYOOKA, S

SHIROUCHI, M

KANEKO, Y

机构：

[1] Department of Chemistry, Kochi University, Kochi, 780, Akebono-cho

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 09期

关键词：

MONOSILYL ACETAL; DIBALH REDUCTION INTERMEDIATE;

D O I：

10.1016/S0040-4039(00)60326-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intermediate generated by the DIBALH reduction of carboxylic acid esters reacts with trimethylsilyl trifluoromethanesulfonate (TMSOTf) in the presence of pyridine to afford the corresponding monosilyl acetals in good yields.

引用

页码：1491 / 1494

页数：4

共 10 条

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