SYNTHESIS, X-RAY STRUCTURE AND ELECTROCHEMICAL PROPERTIES OF A NEW CROWN-ETHER WITH A CIS AZO UNIT IN THE MACROCYCLE

被引：49

作者：

BIERNAT, JF

LUBOCH, E

CYGAN, A

SIMONOV, YA

DVORKIN, AA

MUSZALSKA, E

BILEWICZ, R

机构：

[1] ACAD SCI MOSSR,INST APPL PHYS,KISHINEV 277028,MOLDAVIA,USSR

[2] UNIV WARSAW,DEPT CHEM,PL-02093 WARSAW,POLAND

来源：

TETRAHEDRON | 1992年 / 48卷 / 21期

关键词：

CROWN ETHER; CIS AZO ELECTRON DONOR; VOLTAMMETRY; ION-SELECTIVE ELECTRODE; X-RAY STRUCTURE;

D O I：

10.1016/S0040-4020(01)80448-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chromogenic 13-membered crown ether with a cis azo unit in the macrocycle has been obtained as a side product during the reduction of 1,5-bis(2'-nitrophenoxy)-3-oxapentane. The electrochemical properties of this compound have been studied by the voltammetric method. Its behaviour as an ionophore in ion-selective membrane electrodes has also been investigated. The X-ray structures of the new crown ether 3 and the parent compound 1 have been determined.

引用

页码：4399 / 4406

页数：8

共 21 条

[1] AROMATIC DIAZO AND AZO COMPOUNDS .77. MACROCYCLIC TRISAZO COMPOUNDS WITH AN (18)-ANNULENE-TYPE STRUCTURE [J].