SYNTHESIS OF ALPHA-ALLENIC ALCOHOLS FROM PROPARGYLIC CYCLIC CARBONATES AND SULFITES

被引：19

作者：

KANG, SK

KIM, SG

CHO, DG

机构：

[1] Department of Chemistry, Sung Kyun Kwan University, Suwon, 440-746, Natural Science Campus

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)86046-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of cyclic carbonates or sulfites of acyclic alkynyl diols with organocopper reagents proceeded in S(N)2' fashion and afforded alpha-allenic alcohols of high enantiomeric purity. The stereochemistry of this transformation was shown to be highly anti-diastereoselective.

引用

页码：1509 / 1510

页数：2

共 8 条

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