XANES OF MANGANESE COORDINATION COMPLEXES

被引：11

作者：

Cartier, C. ^{[1
]}

Verdaguer, M. ^{[1
,2
]}

Menage, S. ^{[1
]}

Girerd, J. J. ^{[1
]}

Tuchagues, J. P. ^{[3
]}

Mabad, B. ^{[3
]}

机构：

[1] CNRS, Lab SET, UA 420, F-91405 Orsay, France

[2] Ecole Normale Super, F-92211 St Cloud, France

[3] Chim Coordinat Lab, F-31400 Toulouse, France

来源：

JOURNAL DE PHYSIQUE | 1986年 / 47卷 / C-8期

关键词：

D O I：

10.1051/jphyscol:19868117

中图分类号：

学科分类号：

摘要：

XANES of Mn compounds of known structure and electronic properties [Mn(II), Mn(III), Mn(IV)] is reported. Preedge, Edge and Post-Edge zone are detailed. Dependence on oxidation state, geometry and nuclearity are discussed. Preedge structure is observed and compared with d-orbital splitting obtained from visible NIR spectroscopy. An important Edge shift has been observed with nuclearity and/or geometry change. Post-Edge differences due to stereochemistry are observed for the Mn(III)O-6 chromorhore.

引用

页码：107 / 109

页数：3

共 14 条

[1] Brauer G., 1965, HDB PREPARATIVE INOR
[2] Dockum B.V., INORG CHIM ACTA, V22, P150
[3] CRYSTAL AND MOLECULAR-STRUCTURE OF TRIS(2,4-PENTANEDIONATO)MANGANESE(III), MN(O2C5H7)3, A DISTORTED COMPLEX AS PREDICTED BY JAHN-TELLER ARGUMENTS
FACKLER, JP
AVDEEF, A
[J]. INORGANIC CHEMISTRY, 1974, 13 (08) : 1864 - 1875
[4] HIGHER VALENT MANGANESE CHEMISTRY - SYNTHETIC, STRUCTURAL, AND SOLUTION STUDIES ON [MN(CATECHOLATE)3]N- (N=2,3) COMPLEXES
HARTMAN, JR
FOXMAN, BM
COOPER, SR
[J]. INORGANIC CHEMISTRY, 1984, 23 (10) : 1381 - 1387
[5] HESSEL LW, 1969, RECL TRAV CHIM PAY-B, V88, P545
[6] STRUCTURE OF POTASSIUM TRIS(OXALATO)MANGANATE(III) TRIHYDRATE
LIS, T
MATUSZEWSKI, J
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (AUG): : 1938 - 1940
[7] MANGANESE(II) COMPLEXES OF POLYDENTATE SCHIFF-BASES .1. SYNTHESIS, CHARACTERIZATION, MAGNETIC-PROPERTIES, AND MOLECULAR-STRUCTURE
MABAD, B
CASSOUX, P
TUCHAGUES, JP
HENDRICKSON, DN
[J]. INORGANIC CHEMISTRY, 1986, 25 (09) : 1420 - 1431
[8] Pass G., 1974, PRACTICAL INORGANIC
[9] SUPEROXIDE AND MANGANESE(III) - REACTIONS OF MN-EDTA AND MN-CYDTA COMPLEXES WITH O2- - X-RAY STRUCTURE OF KMNEDTA.2H2O
STEIN, J
FACKLER, JP
MCCLUNE, GJ
FEE, JA
CHAN, LT
[J]. INORGANIC CHEMISTRY, 1979, 18 (12) : 3511 - 3519
[10] TUCHAGUES JP, IN PRESS

← 1 2 →