KINETICS OF THE INTERCALATION OF CATIONS INTO MNPS3 USING REAL-TIME IN-SITU X-RAY-DIFFRACTION

被引：18

作者：

EVANS, JSO ^{[1
]}

OHARE, D ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,S PKS RD,OXFORD OX1 3QR,ENGLAND

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 09期

关键词：

D O I：

10.1002/adma.19940060904

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intercalation in transition metal hexathiohypodiphosphates (MPS3), which proceeds by a unique ion-exchange route, is not well understood because it is difficult to follow the process in real time. Using a recently developed technique that allows the X-ray diffraction pattern of a suspension of an inorganic host lattice in a solution of guest molecules to be recorded in as little as 10 s, the intercalation of cationic species into MnPS3 has been investigated. The analysis of the kinetics at various temperatures is presented.

引用

页码：646 / 648

页数：3

共 20 条

[1] ORGANOMETALLIC INTERCALATES OF THE LAYERED TRANSITION-METAL PHOSPHORUS TRISULFIDES [J].

AUDIERE, JP ;

CLEMENT, R ;

MATHEY, Y ;

MAZIERES, C .

PHYSICA B & C, 1980, 99 (1-4) :133-135

[2] REAL-TIME IN-SITU X-RAY-DIFFRACTION OF INTERCALATION REACTIONS [J].

CLARK, SM ;

EVANS, JSO ;

OHARE, D ;

NUTTALL, CJ ;

WONG, HV .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :809-810

[3]

CLARK SM, IN PRESS REV SCI INS

[4] COORDINATION CHEMISTRY OF THE LAMELLAR MPS3 MATERIALS - METAL-LIGAND CLEAVAGE AS THE SOURCE OF AN UNUSUAL CATION-TRANSFER INTERCALATION PROCESS [J].

CLEMENT, R ;

GARNIER, O ;

JEGOUDEZ, J .

INORGANIC CHEMISTRY, 1986, 25 (09) :1404-1409

[5] ORGANOMETALLIC INTERCALATES OF SOME LAMELLAR METAL PHOSPHORUS TRISULFIDES [J].

CLEMENT, R ;

GREEN, MLH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (10) :1566-1568

[6] DRAMATIC MODIFICATION OF THE MAGNETIC-PROPERTIES OF LAMELLAR MNPS3 UPON INTERCALATION [J].

CLEMENT, R ;

GIRERD, JJ ;

MORGENSTERNBADARAU, I .

INORGANIC CHEMISTRY, 1980, 19 (09) :2852-2854

[7] A NOVEL ROUTE TO INTERCALATION INTO LAYERED MNPS3 [J].

CLEMENT, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (14) :647-648

[8] INTERCALATION OF POTENTIALLY REACTIVE TRANSITION-METAL COMPLEXES IN THE LAMELLAR MNPS3 HOST LATTICE [J].

CLEMENT, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (23) :6998-7000

[9] EXTENDED LAMELLAR SOLIDS VIEWED AS COORDINATION-COMPOUNDS - THE UNIQUE REACTIVITY OF THE MPS3 SERIES [J].

CLEMENT, R ;

DOEUFF, M ;

GLEDEL, C .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1988, 85 (11-12) :1053-1057

[10]

Evans J.D., UNPUB

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