ELECTROPHILIC AROMATIC PROTONATION OF STABLE PI-CARBOCATIONS

被引：13

作者：

PAGNI, RM

SMITH, RJ

机构：

[1] Department of Chemistry, University of Tennessee Knoxville, Tennessee

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 02期

关键词：

D O I：

10.1021/ja00496a052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We noted with interest the recent report of a new type of electrophilic aromatic substitution: the reaction of H+ and D+ with an aromatic cyclopropenyl cation. This highly unusual reaction involves bringing together two positively charged species. We report here that the protonation of aromatic carbocations may be common and much more facile than anyone has imagined. © 1979, American Chemical Society. All rights reserved.

引用

页码：506 / 508

页数：3

共 9 条

[1]

BETHELL D, 1967, CARBONIUM IONS INTRO, pCH4

[2] BASIC STRENGTHS OF SOME AROMATIC ALDEHYDES AND KETONES [J].