Excimer emission and photodimerization in a crystalline stilbene

被引:41
作者
Cohen, M. D. [1 ]
Green, B. S. [1 ]
Ludmer, Z. [1 ]
Schmidt, G. M. J. [1 ]
机构
[1] Weizmann Inst Sci, Dept Chem, IL-76100 Rehovot, Israel
关键词
D O I
10.1016/0009-2614(70)80154-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Crystalline 2. 4-dichloro-trans-stilbene (II) displays excimer emission and undergoes photoreaction to yield the mirror-symmetric dimer 1. cis-2-di(2. 4-dichlorophenyl)-trans-3. trans-4-diphenylcyclo-butane(III). In solution. under a variety of conditions. II shows only monomer emission and yields. in addition to III. the centric photodimer 1. trans-3-di(2. 4-dichlorophenyl)-cis-2. trans-4-diphenylcycle-butane (IV) and cis-monomer.
引用
收藏
页码:486 / 490
页数:5
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