PARTIAL SYNTHESIS OF 7-BETA-HYDROXYEUDESMANOLIDES

被引：8

作者：

COLLADO, IG

MADERO, JG

MASSANET, GM

LUIS, FR

FRONCZEK, FR

机构：

[1] LOUISIANA STATE UNIV,DEPT CHEM,BATON ROUGE,LA 70803

[2] UNIV CADIZ,FAC CIENCIAS,DEPT QUIM ORGAN,E-11510 CADIZ,SPAIN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)97962-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

β-cyclocostunolide has been efficiently transformed into 7-β-hydroxy-β-cyclocostunolide. The key step in the conversion was the rearrangement of the 7β-11β-epoxy derivative with t-BuO-K+/THF. This synthesis supports the biogenetic routes of 7-hydroeudesmanolides. © 1990.

引用

页码：5795 / 5798

页数：4

共 11 条

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