THE ORIGIN OF THE SWELLING OF CLAYS BY WATER

被引：39

作者：

DELVILLE, A ^{[1
]}

LASZLO, P ^{[1
]}

机构：

[1] ECOLE POLYTECH,CHIM FINE BIOMIMET & AUX INTERFACES LAB,F-91128 PALAISEAU,FRANCE

来源：

LANGMUIR | 1990年 / 6卷 / 07期

关键词：

D O I：

10.1021/la00097a017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The diffuse electric double-layer formalism allows calculation of the swelling pressure in good agreement with the observations made on dilute clay suspensions. We correct an error often made in the calculations that renders them incoherent. Analysis of the energies of the clay-water-cation system suggests the importance of solvation of the interlamellar cations. © 1990, American Chemical Society. All rights reserved.

引用

页码：1289 / 1294

页数：6

共 50 条

[1] CHEMICAL POTENTIAL OF HARD-SPHERE FLUIDS BY MONTE-CARLO METHODS
ADAMS, DJ
[J]. MOLECULAR PHYSICS, 1974, 28 (05) : 1241 - 1252
[2] BEYOND POISSON-BOLTZMANN - IMAGES AND CORRELATIONS IN THE ELECTRIC DOUBLE-LAYER .2. SYMMETRIC ELECTROLYTE
ATTARD, P
MITCHELL, DJ
NINHAM, BW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (07) : 4358 - 4367
[3] BARCLAY L, 1970, DISCUSS FARADAY SOC, V1, P138
[4] BOLT G. H., 1955, SOIL SCI SOC AMER PROC, V19, P285
[5] Callaghan I. C., 1974, FARADAY DISCUSS, V57, P110
[6] RADIAL DISTRIBUTIONS OF IONS FOR A PRIMITIVE MODEL OF AN ELECTROYLTE SOLUTION
CARLEY, DD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (10) : 3783 - +
[7] SMALL-ANGLE NEUTRON-SCATTERING FROM DILUTE AQUEOUS DISPERSIONS OF CLAY
CEBULA, DJ
THOMAS, RK
WHITE, JW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1980, 76 : 314 - 321
[8] COOKER H, 1976, J PHYS CHEM-US, V80, P2084
[9] DELVILLE A, 1989, NEW J CHEM, V13, P481
[10] DELVILLE A, 1984, NOUV J CHIM, V8, P557

← 1 2 3 4 5 →