PREPARATION AND STRUCTURE OF HEXACHLOROTETRAPYRIDINE DITANTALUM(III)

被引：9

作者：

BABAIANKIBALA, E

COTTON, FA

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843

[2] TEXAS A&M UNIV SYST,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

INORGANICA CHIMICA ACTA | 1990年 / 171卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)84666-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, Ta2Cl6py4, has been prepared and structurally characterized. It is very similar to its tungsten analog, from which some inferences concerning the MM bonding in both compounds may be drawn. The principal dimensions of the molecule are: TaTa, 2.740(1); TaClb, 2.44[1]; TaClax, 2.400[6]; TaCleq, 2.46[1]; TaNax, 2.216[3]; TaNeq, 2.31 [2] Å. © 1990.

引用

页码：71 / 74

页数：4

共 7 条

[1] FURTHER STUDY OF METAL METAL BOND LENGTHS IN HOMOLOGOUS EDGE-SHARING BIOCTAHEDRAL COMPLEXES
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COTTON, FA
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[2] SYNTHESIS AND CHARACTERIZATION OF SOME MONOMERIC NIOBIUM(III) COMPLEXES
CLAY, ME
BROWN, TM
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1982, 58 (MAR): : 1 - 3
[3] THE STRUCTURES OF METAL METAL-BONDED EDGE-SHARING BIOCTAHEDRAL COMPLEXES
COTTON, FA
[J]. POLYHEDRON, 1987, 6 (04) : 667 - 677
[4] NEW DINUCLEAR AND TRINUCLEAR COMPLEXES OF RUTHENIUM WITH OCTAHEDRA JOINED ON FACES OR EDGES - RU2CL6(PBU3)3, RU2CL6(PBU3)4, AND RU3CL8(PBU3)4 (BU = CH3CH2CH2CH2)
COTTON, FA
MATUSZ, M
TORRALBA, RC
[J]. INORGANIC CHEMISTRY, 1989, 28 (08) : 1516 - 1520
[5] COTTON FA, 1988, INORG CHEM, V27, P779
[6] JACKSON RB, 1971, INORG CHEM, V10, P1760
[7] METAL-METAL-BONDED COMPLEXES OF THE EARLY TRANSITION-METALS .4. SYNTHESIS AND CHARACTERIZATION OF THE TANTALUM(III) DIMER TA2CL6(PME3)4
SATTELBERGER, AP
WILSON, RB
HUFFMAN, JC
[J]. INORGANIC CHEMISTRY, 1982, 21 (06) : 2392 - 2396

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