The Theory of the Glass Electrode. III Statistical Explanation of the Alkaline Solution Behavior

被引：29

作者：

Dole, Malcolm ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1934年 / 2卷 / 12期

关键词：

D O I：

10.1063/1.1749409

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The application of Gurney's quantum and statistical mechanical theory of electrochemistry to the glass electrode results in an equation for the alkaline solution behavior identical with one previously obtained by the author except that the constants of the equation have a more reasonable significance. A qualitative explanation of the inability of negative ions to affect the glass electrode potentials is also given.

引用

页数：5

共 11 条

[1]

[Anonymous], 1934, T FARADAY SOC, V30, P461

[2]

[Anonymous], 1931, J AM CHEM SOC, V53, P4260

[3]

[Anonymous], 1931, Z PHYS CHEM A, VA156, P232

[4] The theory of the glass electrode. II. The glass as a water electrode [J].

Dole, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1932, 54 :3095-3105

[5] The theory of the glass electrode [J].

Dole, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1931, 53 :4260-4280

[6] On the Theory of Glass Electrodes [J].

Gross, Philipp ;

Halpern, Otto .

JOURNAL OF CHEMICAL PHYSICS, 1934, 2 (03)

[7] The quantum mechanics of electrolysis. [J].

Gurney, RW .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1931, 134 (823) :137-154

[8] The quantum mechanics of electrochemistry - II [J].

Gurney, RW .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1932, 136 (829) :378-396

[9]

MACINNES, 1931, J AM CHEM SOC, V53, P3315

[10]

Ssokolof S, 1932, Z PHYS CHEM A-CHEM T, V160, P366

← 1 2 →