TRIPHENYLBISMUTH DIACYLATES AS NOVEL REAGENTS FOR FINE ORGANIC-SYNTHESIS

被引：22

作者：

DODONOV, VA

GUSHCHIN, AV

机构：

[1] N. I. Lobachevsky Nyzhnii Novgorod State University, Nyzhnii Novgorod, 603600

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 12期

关键词：

TRIPHENYLBISMUTH DIACYLATES; OXIDATION; PHENYLATION; ALCOHOLS; DIOLS; ENOLS; PHENOLS; AMINES; AMINOESTERS;

D O I：

10.1007/BF00698873

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triphenylbismuth diacylates, Ph(3)Bi(O(2)CR)(2) (R = Me, Et, Ph, CF3, CH=CH2), are novel effective reagents for fine organic synthesis. They oxidize primary and secondary alcohols and di-tert-glycols under mild conditions to form the corresponding carbonyl compounds in high yields; O- and N-phenylate alcohols, enols, and amines; and O- and o-C-phenylate phenols.

引用

页码：1955 / 1959

页数：5

共 18 条

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