THE ROLE OF DOPING IN ELECTROCHEMICAL SYNTHESIS OF CONDUCTIVE POLYMERS

被引:13
作者
KOBRYANSKII, VM
ARNAUTOV, SA
机构
[1] Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Kosygin st.
关键词
D O I
10.1016/0379-6779(93)90253-S
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A hypothesis which considers the role of doping of marcromolecules generated in the process of polyphenylene synthesis, is proposed. Such, flexible transparent high-molecular (n>90) films of polyphenylene were obtained by electrochemical polymerization of benzene in aluminum chloride and butylpyridiniumchloride based ionic liquid under high potential. Effects of the process parameters on the structure and molecular mass of the samples were studied.
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页码:1371 / 1376
页数:6
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