A NEW APPROACH TO MODELING THE CURE KINETICS OF EPOXY AMINE THERMOSETTING RESINS .1. MATHEMATICAL DEVELOPMENT

被引：128

作者：

COLE, KC

机构：

[1] Industrial Materials Research Institute, National Research Council of Canada, Boucherville, Québec, J4B 6Y4

来源：

MACROMOLECULES | 1991年 / 24卷 / 11期

关键词：

D O I：

10.1021/ma00011a011

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The Horie model for describing the cure kinetics of epoxy amine systems is extended to explicitly include the etherification reaction, which becomes significant when there is an excess of epoxy with respect to amine and when the cure is performed at higher temperatures. A solution to the kinetic equations is derived that makes it possible to determine the relationship between the degree of conversion alpha and the rate of conversion d-alpha/dt. Different possible mechanisms for the etherification reaction are considered. The model can be used to calculate the amounts of different groups formed in the reaction and hence provide information concerning the network structure.

引用

页码：3093 / 3097

页数：5

共 14 条

[1]

BARTON JM, 1985, ADV POLYM SCI, V72, P111

[2] ANALYSIS OF THE SUBSTITUTION EFFECTS INVOLVED IN DIEPOXIDE-DIAMINE COPOLYMERIZATION REACTIONS [J].