APPLICATION OF THE THEORY OF DISPERSION FORCES TO THE SURFACE MELTING OF ICE

被引:153
作者
ELBAUM, M [1 ]
SCHICK, M [1 ]
机构
[1] UNIV OSLO,DEPT PHYS,N-0316 OSLO 3,NORWAY
关键词
D O I
10.1103/PhysRevLett.66.1713
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We apply the theory of Dzyaloshinskii, Lifshitz, and Pitaevskii to ice, water, and vapor at the triple point and find that electromagnetic interactions do not permit a liquid film of macroscopic thickness at the ice-vapor interface. Hence the surface melting of ice is at most incomplete. However, the thickness of the film which is permitted is surprisingly large, with retardation effects setting the scale. Our estimate is about 30 angstrom. Further liquid appears as droplets with a contact angle of about 0.2-degrees. The film thickness decreases rapidly with temperature.
引用
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页码:1713 / 1716
页数:4
相关论文
共 26 条
[1]  
BARASH YS, 1989, DIELECTRIC FUNCTION
[2]  
Daniels J., 1971, Optics Communications, V3, P240, DOI 10.1016/0030-4018(71)90012-5
[3]   THERMOMOLECULAR PRESSURE IN SURFACE MELTING - MOTIVATION FOR FROST HEAVE [J].
DASH, JG .
SCIENCE, 1989, 246 (4937) :1591-1593
[4]  
DASH JG, 1988, 19 P SOLV C
[5]  
Dietrich S., 1988, PHASE TRANSITIONS CR, V12
[6]   THE GENERAL THEORY OF VANDERWAALS FORCES [J].
DZYALOSHINSKII, IE ;
LIFSHITZ, EM ;
PITAEVSKII, LP .
ADVANCES IN PHYSICS, 1961, 10 (38) :165-209
[7]   SURFACE STRUCTURE OF WATER AND ICE .2. A REVISED MODEL [J].
FLETCHER, NH .
PHILOSOPHICAL MAGAZINE, 1968, 18 (156) :1287-&
[8]  
FORLAND KS, 1988, IRREVERSIBLE THERMOD, P235
[9]   OBSERVATION OF SURFACE MELTING [J].
FRENKEN, JWM ;
VANDERVEEN, JF .
PHYSICAL REVIEW LETTERS, 1985, 54 (02) :134-137
[10]  
GRIFFITHS RB, 1980, PHASE TRANSITIONS CR