VOLTAMMETRIC STUDIES ON THE ELECTROPOLYMERIZATION MECHANISM OF METHOXYTHIOPHENES

被引：25

作者：

TSCHUNCKY, P

HEINZE, J

机构：

[1] Institut für Physikalische Chemie der Universität Freiburg, Freiburg

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 2-3期

关键词：

D O I：

10.1016/0379-6779(93)90292-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Fast scan cyclic voltammetry has been used to investigate the polymerisation kinetics of different methoxy-substituted thiophene derivatives. The voltammograms prove decreasing dimerization constants with increasing chain length of the electroactivated radical cation. The influence of the position of substitution on the reaction kinetics could be outlined by comparison of the reaction kinetics of 3,3'- and 4,4'-dimethoxy-2,2'-dithiophene

引用

页码：1603 / 1607

页数：5

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