TETRACARBONYL[1-PHENYL-N-(2-PYRIDYLMETHYLIDENE)ETHYLAMINE-N,N']MOLYBDENUM(0)

被引：12

作者：

ALYEA, EC

FERGUSON, G

JAIN, VK

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194003197

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Mo atom in the title complex, [MO(CO)4(C14H14N2)] (I), is in a distorted octahedral environment. The Mo-C distances trans to each N atom [1.944 (5), 1.955 (4) angstrom] are significantly shorter than those cis to both N atoms [2.031 (5), 2.045 (4) angstrom]. The carbonyl groups cis to both N atoms are bent away from the nitrogen-donor ligand with Mo-C-O angles of 172.1 (4) and 173.9 (4)-degrees.

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页码：854 / 857

页数：4

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