HIGHLY POLARIZABLE BIARYL SALTS FOR LIQUID-CRYSTALS AND NONLINEAR OPTICS - SYNTHESIS AND PROPERTIES OF A PHENOL PYRIDINIUM TRIFLATE

被引:5
作者
BOY, P
COMBELLAS, C
MATHEY, G
PALACIN, S
PERSOONS, A
THIEBAULT, A
VERBIEST, T
机构
[1] CEA SACLAY,SERV CHIM MOLEC,F-91191 GIF SUR YVETTE,FRANCE
[2] CATHOLIC UNIV LEUVEN,DEPT CHEM,B-3030 HEVERLEE,BELGIUM
关键词
D O I
10.1002/adma.19940060712
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A nonlinear waveguide material with a good transparency/efficiency trade-off is presented. The synthesis of the biaryl-based salt and its mesomorphic and nonlinear optical properties, including second harmonic generation from floating Langmuir-Blodgett layers, are described. The advantages of this new phenol/pyridinium triflate, which exhibits mesomorphic properties over a 50-degrees-C range, compared to the uncharged and zwitterionic analogues are discussed.
引用
收藏
页码:580 / 583
页数:4
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