SYNTHESIS, SPECTRUM AND SINGLE-CRYSTAL STRUCTURE OF A PEROXOVANADIUM COMPLEX OF NITRILOTRIACETATE LIGAND WITHOUT WATER OF CRYSTALLIZATION, K2[VO(O2)NTA]

被引：13

作者：

WEI, YG ^{[1
]}

ZHANG, SW ^{[1
]}

HUANG, GQ ^{[1
]}

SHAO, MC ^{[1
]}

机构：

[1] BEIJING UNIV,DEPT CHEM,BEIJING 100871,PEOPLES R CHINA

来源：

POLYHEDRON | 1994年 / 13卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)83454-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of the formula K2[VO(O2)NTA] with NTA = nitrilotriacetate have been prepared and characterized by IR and single-crystal X-ray diffraction methods. The structure of the anion of the complex shows that the vanadium atom has a distorted pentagonal bipyramidal environment surrounded by one oxo group, one peroxo group, three oxygen atoms and one nitrogen atom from the NTA ligand.

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页码：1587 / 1591

页数：5

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