DIELECTRIC BEHAVIOR OF POLYCRYSTALLINE LEAD GERMANATE

被引:21
作者
MANSINGH, A [1 ]
SRIVASTAVA, KN [1 ]
SINGH, B [1 ]
机构
[1] DEF SCI LAB,DELHI 110054,INDIA
关键词
D O I
10.1016/0022-3697(79)90089-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The dielectric behaviour of ferroelectric Lead Germanate (Pb5Ge3O11) is reported in the frequency region 60 Hz-100 KHz for various particle size ranges from 40 to 300 μ m. The dielectric constant and conductivity decrease with decreasing particle size. The dielectric anomaly in small particle size unsintered samples disappears at lower frequencies, while at 100 KHz a broad diffuse phase transition is observed for all the samples, irrespective of particle size. A strong dielectric dispersion has been observed in the frequency range 60 Hz-100 KHz. The dielectric constant of sintered samples for the same panicle size range, and the dielectric anomaly which was absent at lower frequencies for unsintered samples re-appears in sintered samples. These results have been explained by assuming a high resistivity surface layer having a lower dielectric constant than the bulk at the boundary of particles. © 1979.
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页码:9 / 15
页数:7
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