THE COPPER(I)-CATALYZED COUPLING OF GRIGNARD-REAGENTS WITH 5-LITHIO-2,3-DIHYDROFURAN AND 6-LITHIO-3,4-DIHYDRO-2H-PYRAN

被引：17

作者：

BARBER, C ^{[1
]}

BURY, P ^{[1
]}

KOCIENSKI, P ^{[1
]}

OSHEA, M ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 22期

关键词：

D O I：

10.1039/c39910001595

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The organocuprates derived from reaction of Grignard reagents with CuBr.Me2S react with 5-lithio-2,3-dihydrofuran and 6-lithio-3,4-dihydro-2H-pyran via a 1,2-metallate rearrangement to generate an alkenylmagnesium cuprate.

引用

页码：1595 / 1597

页数：3

共 4 条

[1] SYNTHETIC APPLICATIONS OF METALLATE REARRANGEMENTS
KOCIENSKI, P
BARBER, C
[J]. PURE AND APPLIED CHEMISTRY, 1990, 62 (10) : 1933 - 1940
[2] A STEREOSELECTIVE SYNTHESIS OF FUNCTIONALIZED ALKENYLLITHIUMS AND ALKENYL CYANOCUPRATES BY THE CU(I)-CATALYZED COUPLING OF ORGANO-LITHIUM REAGENTS WITH ALPHA-LITHIATED CYCLIC ENOL ETHERS
KOCIENSKI, P
WADMAN, S
COOPER, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) : 2363 - 2365
[3] A SYNTHESIS OF THE C16-C23 SEGMENT OF FK-506
STOCKS, M
KOCIENSKI, P
DONALD, DK
[J]. TETRAHEDRON LETTERS, 1990, 31 (11) : 1637 - 1640
[4] A NEW APPROACH TO 1,7-DIOXASPIRO[5.5]UNDEC-4-ENES VIA METALATED ALLENOL ETHERS - SYNTHESIS OF LACRIMIN-A
TAKLE, A
KOCIENSKI, P
[J]. TETRAHEDRON, 1990, 46 (13-14) : 4503 - 4516

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