SYNTHESIS OF MONODISPERSED BIMETALLIC PALLADIUM COPPER NANOSCALE COLLOIDS

被引：135

作者：

BRADLEY, JS ^{[1
]}

HILL, EW ^{[1
]}

KLEIN, C ^{[1
]}

CHAUDRET, B ^{[1
]}

DUTEIL, A ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

CHEMISTRY OF MATERIALS | 1993年 / 5卷 / 03期

关键词：

D O I：

10.1021/cm00027a005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mixtures of palladium acetate and copper acetate were refluxed in 2-ethoxyethanol in the presence of poly(vinylpyrrolidone) to give 40-angstrom alloy nanoclusters. TEM and EDAX analysis showed that the particles were homogeneously bimetallic and crystalline, with a composition determined by the ratio of the metal acetates used. Carbon monoxide adsorbed on the colloidal particles binds reversibly to both metals.

引用

页码：254 / 256

页数：3

共 20 条

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