STRUCTURE OF SOLVATED ION-PAIRS FROM ELECTRIC-DIPOLE MOMENTS

被引：8

作者：

GRUNWALD, E ^{[1
]}

I, TP ^{[1
]}

机构：

[1] PFIZER INC,CENT RES,GROTON,CT 06340

来源：

PURE AND APPLIED CHEMISTRY | 1979年 / 51卷 / 01期

关键词：

D O I：

10.1351/pac197951010053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Theory and complications involved in dipole moment measurements in slightly conductive polar solvents are discussed. Experimental results are presented for the following electrolytes in anhydrous acetic acid: LiCl, KCl, KBr, LiTs, KTs, CsTs, TlTs, R4NNO3, BHTs, Ts = p-toluenesulfonate; BH = p-toluidinium; R4N = tetra-isoamylammonium. Except for R4NNO3, the dipole moments indicate that solvation complexes are formed between the respective ion pairs and acetic acid molecules. Comparison of dipole moments of the solvation complexes with intrinsic dipole moments of the ion pairs yields information about the structure of the solvation complexes. © 1979, Walter de Gruyter. All rights reserved.

引用

页码：53 / 61

页数：9

共 22 条

[1] BAUGE K, 1964, J CHEM SOC, P244
[2] DERIVATION OF KIRKWOOD-FROHLICH EQUATION
BORDEWIJK, P
[J]. PHYSICA, 1973, 69 (02): : 422 - 432
[3] BOTTCHER CJF, 1952, THEORY ELECTRIC POLA
[4] HYDROGEN-BONDING IN POLAR LIQUID SOLUTIONS .3. EFFECTS OF NON-HYDROGEN-BONDING SOLUTES ON DIELECTRIC-CONSTANT OF HYDROXYLIC SOLVENTS
GRUNWALD, E
ANDERSON, SP
EFFIO, A
GOULD, SE
PAN, KC
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (27) : 2935 - 2937
[5] HYDROGEN-BONDING IN POLAR LIQUID SOLUTIONS .1. DEVELOPMENT OF KIRKWOODS DIELECTRIC THEORY IN TERMS OF A CHEMICAL-MODEL
GRUNWALD, E
PAN, KC
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (27) : 2929 - 2931
[6] MOLECULAR-STRUCTURE OF ION-PAIRS FROM ELECTRIC-DIPOLE MOMENTS .4. ION-PAIR SOLVATION IN ACETIC-ACID
GRUNWALD, E
CRAMPTON, MR
EFFIO, A
I, TP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (07) : 1716 - 1720
[7] GRUNWALD E, 1974, IONS ION PAIRS ORGAN, V2
[8] Electric Dipole Moments in Polar Solvents. I. Audiofrequency Measurement with Slightly Conducting Solutions
Grunwald, Ernest
Effio, Adan
[J]. JOURNAL OF SOLUTION CHEMISTRY, 1973, 2 (04) : 373 - 392
[9] GRUNWALD TP, 1974, J AM CHEM SOC, V96, P2387
[10] GRUNWALD TPI, 1974, J AM CHEM SOC, V96, P2879

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