CALCULATION OF J-2(HH) COUPLINGS IN BENZYL GROUPS

被引：5

作者：

ABRAHAM, RJ ^{[1
]}

BAKKE, JM ^{[1
]}

机构：

[1] UNIV TRONDHEIM,DEPT CHEM,NLHT,N-7000 TRONDHEIM,NORWAY

来源：

ORGANIC MAGNETIC RESONANCE | 1978年 / 11卷 / 07期

关键词：

D O I：

10.1002/mrc.1270110711

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The results of FPT/INDO theory together with the observed 2J(HH) coupling in benzyl groups (Ph · CH2X) leads to a simple equation 2J(HH) = A+B cos θ+C cos 2θ where θ is the C.C.C.X dihedral angle, and X = C,H. The extension to other X substituents can be obtained from additivity rules. Copyright © 1978 Heyden & Son Ltd.

引用

页码：373 / 374

页数：2

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