REACTIVITY OF ORTHO-N,N-DIMETHYLAMINOTOLUENE WITH PALLADIUM(II) COMPOUNDS, CYCLOMETALLATION AND DEMETHYLATION OF THE NITROGEN ATOM

被引：32

作者：

MUTET, C ^{[1
]}

PFEFFER, M ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,CHIM COORDINAT LAB,F-67070 STRASBOURG,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)81548-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

o-N,N-Dimethylaminotoluene (dmat) reacts with Li2PdCl4 in methanol to give trans-Pd(mat)2Cl2 (mat = o-N-methylaminotoluene) by demethylation of the nitrogen. With Pd(PhCN)2Cl2 in dichloromethane an unstable dimeric adduct of the tertiary amine is obtained. With palladium acetate cyclopalladation occurs by metallation of the ortho-methyl group, while the reaction with palladium trifluoroacetate affords trans-Pd(dmat)2(O2CCF3)2. © 1979.

引用

页码：C34 / C36

页数：3

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