2 FUNCTIONALIZED FREE-RADICALS OF THE TRIS(2,4,6-TRICHLOROPHENYL)METHYL RADICAL SERIES - SYNTHESIS, STABILITY AND EPR ANALYSIS

被引：36

作者：

CARILLA, J

FAJARI, L

JULIA, L

RIERA, J

VIADEL, L

机构：

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)78264-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tris(2,4,6-trichlorophenyl)carbenium hexachloro-antimonate (2), (2,6-dichloro-4-hydroxyphenyl)bis(2,4,6-trichlorophenyl)methyl radical (4) and its methyl ether derivative 5 have been synthesized and isolated as crystalline solids. In contrast to 5, radical 4 is not very stable in air, and the disappearance of 4 by aerial oxidation has been monitored by UV-vis spectroscopy. The EPR spectra of 4 and 5 are reported and commented upon.

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页码：6529 / 6532

页数：4

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