REACTIVITY OF RUTHENIUM 5,10,15,20-TETRAMESITYLPORPHYRIN TOWARDS DIAZOESTERS - FORMATION OF OLEFINS

被引：73

作者：

COLLMAN, JP

ROSE, E

VENBURG, GD

机构：

[1] UNIV PARIS 06,CHIM ORGAN LAB,F-75252 PARIS 05,FRANCE

[2] ABBOTT LABS,DEPT 91J,ABBOTT PK,IL 60064

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期

关键词：

D O I：

10.1039/c39930000934

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium 5,10,15,20-tetramesitylporphyrin, Ru(tmp), reacts with 1 equiv. of N2CHCO2Et to afford the ethoxycarbonylcarbene [Ru(tmp)=CHCO2Et] in the presence of an excess of N2CHCO2Et; the latter catalyses the formation of diethyl maleate as the major product at a rate of approximately one turnover per second.

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页码：934 / 935

页数：2

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