PREPARATION OF 1,1'-BIS[(DIPHENYLPHOSPHINO)METHYL]FERROCENE AND ITS TRANSITION-METAL COMPLEXES

被引：37

作者：

YAMAMOTO, Y

TANASE, T

MORI, I

NAKAMURA, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 21期

关键词：

D O I：

10.1039/dt9940003191

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1'-Bis[(diphenylphosphino)methyl]ferrocene (dpmf), prepared from 1,1'-bis(chloromethyl)ferrocene and LiPPh2, reacted with [PdCl2(MeCN)2] to give [Pd2Cl2(dpmf2] 1, and treatment of 1 with [Pd3(2,6-Me2C6H3NC)6] in a 1 : 0.66 ratio in the presence of NH4PF6 and 2,6-Me2C6H3NC produced a macrocyclic complex [Pd4(2,6-Me2C6H3NC)8(dpmf)2]4+.

引用

收藏

页码：3191 / 3192

页数：2

相关论文

共 10 条

[1] 1,1'-BIS[(ALKYL/ARYL)PHOSPHINO]FERROCENES - SYNTHESIS AND METAL-COMPLEX FORMATION - CRYSTAL-STRUCTURE OF 3 METAL-COMPLEXES OF FE(ETA-5-C5H4PPH2)2- [J].

BUTLER, IR ;

CULLEN, WR ;

KIM, TJ ;

RETTIG, SJ ;

TROTTER, J .

ORGANOMETALLICS, 1985, 4 (06) :972-980

[2]

CLEMENTE DA, 1986, INORG CHIM ACTA, V115, pL93

[3] IRON OSMIUM BONDING IN CLUSTERS CONTAINING FERROCENE FRAGMENTS [J].

CULLEN, WR ;

RETTIG, SJ ;

ZHENG, TC .

ORGANOMETALLICS, 1992, 11 (01) :277-283

[4] THERMOLYSIS OF OS3(CO)10[FE(ETA-C5H4PPRI2)2] - CRYSTAL AND MOLECULAR-STRUCTURES OF (MU-H)OS3(CO)8[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRICHMECH2CO)], (MU-H)OS3(CO)9[MU-(ETA-C5H4PPRI2)FE(ETA-C5H4PPRI)], AND (MU-H)2OS3(CO)8[ETA-3-MU-(ETA-C5H4PPRI2)FE(ETA-C5H3PPRI)] [J].

CULLEN, WR ;

RETTIG, SJ ;

ZHENG, TC .

ORGANOMETALLICS, 1993, 12 (03) :688-696

[5] STRUCTURES OF 3 HYDROGENATION CATALYSTS [(P-P)RH(NBD)]CIO4 AND SOME COMPARATIVE RATE STUDIES WHERE (P-P)=(ETA-5-R1R2PC5H4)(ETA-5-R3R4PC5H4)FE (R1=R2=R3=R4=PH,R1=R2=PH,R3=R4=CME,R1=R3=PH,R2=R4=CME3) [J].

CULLEN, WR ;

KIM, TJ ;

EINSTEIN, FWB ;

JONES, T .

ORGANOMETALLICS, 1985, 4 (02) :346-351

[6] DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM-(II) - AN EFFECTIVE CATALYST FOR CROSS-COUPLING OF SECONDARY AND PRIMARY ALKYL GRIGNARD AND ALKYLZINC REAGENTS WITH ORGANIC HALIDES [J].

HAYASHI, T ;

KONISHI, M ;

KOBORI, Y ;

KUMADA, M ;

HIGUCHI, T ;

HIROTSU, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (01) :158-163

[7] HETEROPOLYMETALLIC COMPLEXES OF 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF) .7. REDOX BEHAVIOR OF DPPF [J].

PILLONI, G ;

LONGATO, B ;

CORAIN, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 420 (01) :57-65

[8]

SANGER AR, 1976, J CHEM SOC DA, P322

[9] REACTIONS OF FERROCENYLCARBENE .4. SYNTHESIS OF [3]-FERROCENOPHAN-2-ONE TOSYLHYDRAZONE AND THERMAL DECOMPOSITION OF ITS SODIUM SALT [J].

SONODA, A ;

MORITANI, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 26 (01) :133-&

[10]

YAMAMOTO Y, 1993, ORGANOMETALLICS, V12, P993