CYCLOADDITION OF NITRILE OXIDES TO HOMOCHIRAL VINYL ETHERS

被引：13

作者：

BOA, AN ^{[1
]}

BOOTH, SE ^{[1
]}

DAWKINS, DA ^{[1
]}

JENKINS, PR ^{[1
]}

FAWCETT, J ^{[1
]}

RUSSELL, DR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 12期

关键词：

D O I：

10.1039/p19930001277

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the [3 + 2] cycloaddition of a range of nitrile oxides with homochiral vinyl ethers the diastereoselectivity observed is dependent on the chiral auxiliary used; an X-ray structure determination of the major isomer of product 11a, from the reaction of benzonitrile oxide and (S)-1-(2-naphthyl)-ethyl vinyl ether, is consistent with the proposed preferred conformation of the vinyl ether.

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页码：1277 / 1278

页数：2

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