LOW-VALENT METAL-COMPLEXES AS REDOXACTIVE LIGANDS - NEW HETEROPOLYNUCLEAR DERIVATIVES OF MANGANESE AND RHENIUM CYANIDES AND THE CRYSTAL-STRUCTURE OF [(O-PHEN)(OC)3RE(MU-CN)RU(CO)2(PPH3)(O-O2C6CL4)]

被引：8

作者：

BARDAJI, M ^{[1
]}

BROWN, NC ^{[1
]}

CONNELLY, NG ^{[1
]}

DAVIES, R ^{[1
]}

ORPEN, AG ^{[1
]}

ROSAIR, GM ^{[1
]}

SEEAR, NR ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 474卷 / 1-2期

关键词：

MANGANESE; RHENIUM; CYANIDE; ELECTROCHEMISTRY; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)84078-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New redox-active homo- and heteropolynuclear complexes, including the X-ray structurally characterised species [(o-phen)(OC)3-Re(mu-CN)RU(CO)2(PPh3)(o-O2C6Cl4)], have been constructed using the cyanometal ligands [Mn(CN)L(NO)Cp'] (Cp'= eta-C5H4Me) and [Re(CN)(CO)3(N-N)] (N-N = bipy, o-phen, etc.).

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页码：C21 / C23

页数：3

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