NEW HALIDE GLASSES [THE SYSTEM CDCL2-PBCL2-KI-PBO]

被引：5

作者：

FRUMAROVA, B ^{[1
]}

FRUMAR, M ^{[1
]}

MALEK, J ^{[1
]}

机构：

[1] UNIV PARDUBICE,CS-53210 PARDUBICE,CZECH REPUBLIC

来源：

MATERIALS RESEARCH BULLETIN | 1994年 / 29卷 / 10期

关键词：

GLASSES; HALIDES; LEAD; CADMIUM;

D O I：

10.1016/0025-5408(94)90084-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

New glasses of composition 30 CdCl2- 50 PbCl2- 30 KI doped with 0.1; 0.5; 3, 5; 10; 15; 25 or 30 mol% PbO were prepared and their thermal (T(g), T(x), T(c), T(m)), and optical (T, R, diffuse reflectivity) properties from the visible to the far IR region were determined. The glass-forming ability is enhanced by doping with lead oxide and glasses of thickness up to 1 cm can be prepared. The glass transition temperature T(g) of investigated glasses is in the 84-120-degrees-C range, the temperature of crystallization T(c) is in the 122-146-degrees-C domain. The glasses are transparent from 22000 cm-1 up to 1000 cm-1. The origin of IR absorption bands near 3450, 900 and 365 cm-1 is discussed.

引用

页码：1035 / 1040

页数：6

共 8 条

[1]

FRUMAR M, 1989, MATERIALS SCI MONOGR, V60

[2]

HORAK M, 1976, INFRACERVENA SPEKTRA, P254

[3]

Kortum G., 1969, REFLECTANCE SPECTROS, P106

[4]

Nyquist RA, 1971, VIB SPECTROSC, DOI [10.1016/C2009-0-22109-X, DOI 10.1016/C2009-0-22109-X]

[5] NEW HALIDE GLASSES OF THE CDX2-PBX2-KL (X = CL, BR) SYSTEMS [J].

PETROVA, B ;

FRUMAR, M ;

STRANSKA, E ;

HLOZANEK, I .

JOURNAL OF MATERIALS SCIENCE, 1989, 24 (12) :4555-4556

[6]

RAO BG, 1984, PHYS CHEM GLASSES, V25, P11

[7]

SAAD M, 1987, 4TH P INT S HAL GLAS, P48

[8]

ZEFIROFF AP, 1965, TERMODYNAMICHESKYE S

← 1 →