HETERODIMETALLIC COMPLEXES WITH AN UNBRIDGED, POLAR METAL-METAL BOND

被引：41

作者：

HERBERHOLD, M

JIN, GX

机构：

[1] Laboratorium für Anorganische Chemie, Universität Bayreuth, D-95440

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199409641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metal–metal bonds are stable without bridging ligands in the heterodinuclear complexes 1 and 2. The combination of one metal center in a high oxidation state and one in a low oxidation state causes these bonds to be strongly polarized. The reactivity of such systems promises to be interesting–recently the direct insertion of CO2 into the ZrFe and ZrRu bond of related complexes has been achieved. R = p‐tolyl. (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：964 / 966

页数：3

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