UNUSUAL SLOPES OF FREE ENERGY PLOTS IN KINETICS

被引：269

作者：

MARCUS, RA

机构：

[1] W. A. Noyes Chemical Laboratory, University of Illinois, Urbana

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 26期

关键词：

D O I：

10.1021/ja01054a003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Theoretical equations1 are used to comment on the relation between the slope of activation free energy-standard free energy of reaction plots and the concept of the position of the transition state along the reaction coordinate. The equations are then used to consider some recent experimental findings of unusual Br⊘nsted coefficients. © 1969, American Chemical Society. All rights reserved.

引用

页码：7224 / &

共 7 条

[1] BRONSTED COEFFICIENTS LARGER THAN 1 AND LESS THAN 0 FOR PROTON REMOVAL FROM CARBON ACIDS [J].

BORDWELL, FG ;

BOYLE, WJ ;

HAUTALA, JA ;

YEE, KC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (14) :4002-&

[2] ON SLOPE OF FREE ENERGY PLOTS IN CHEMICAL KINETICS [J].

COHEN, AO ;

MARCUS, RA .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) :4249-&

[3] IMPORTANCE OF ALPHA EFFECT IN AMINE GENERAL BASE CATALYZED IONIZATION OF NITROETHANE [J].

GREGORY, MJ ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (10) :2327-&

[4]

LEVICH VG, 1968, ELECTROCHIM ACTA, V13, P1025

[5]

LEVICH VG, 1967, ELECTROKHYMIYA, V3, P739

[6] ON THE THEORY OF OXIDATION-REDUCTION REACTIONS INVOLVING ELECTRON TRANSFER .1. [J].

MARCUS, RA .

JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (05) :966-978

[7] THEORETICAL RELATIONS AMONG RATE CONSTANTS BARRIERS AND BRONSTED SLOPES OF CHEMICAL REACTIONS [J].

MARCUS, RA .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (03) :891-&

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