POTASSIUM FLUORIDE ACTIVATED ALCOHOLYSIS OF HINDERED SILIRANES

被引：8

作者：

KUMARATHASAN, R ^{[1
]}

BOUDJOUK, P ^{[1
]}

机构：

[1] N DAKOTA STATE UNIV,DEPT CHEM,FARGO,ND 58105

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)94479-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rate of alcoholysis of 1,1-di-t-butylsiliranes is significantly accelerated in the presence of 10% KF and still further enhanced by the addition of 1% 18-crown-6. A pentacoordinate siliconate is proposed as the intermediate responsible for the observed rate increases. © 1990.

引用

页码：3987 / 3990

页数：4

共 8 条

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