ISOCHORIC (P,V,T) MEASUREMENTS ON C2H4F2(R152A) IN THE LIQUID-STATE FROM THE TRIPLE POINT TO 450-K AND AT PRESSURES UP TO 30 MPA

被引:28
作者
BLANKE, W
WEISS, R
机构
关键词
1,1-DIFLUOROETHANE (C2H4F2, R152A); ISOCHORIC; (P; V; T); MEASUREMENTS; TRIPLE POINT; VAPOR PRESSURE; SATURATION DENSITY;
D O I
10.1016/0378-3812(92)87066-V
中图分类号
O414.1 [热力学];
学科分类号
摘要
The investigations of the thermodynamic properties of R152a (purity: at least 99,99%) were focussed on the measurement of the pressure/temperature dependence along 17 quasi-isochores in the liquid single-phase region. This region of state, which was investigated using two apparatuses, extended from the triple point to 450 K. The relative uncertainty of the measurements - related to the quotient pv/(RT) - is less than 1.10(-3). The (p, v ,T) data measured can be reproduced within their uncertainty of measurement with the aid of a correlation equation with 11 substance-specific constants. In the temperature range above 200 K, the measured values are in good agreement with data given in the literature. In addition to the investigation of the (p, v ,T) properties, temperature and pressure at the triple point were measured for the first time. on the basis of vapour pressure measurements up to 260 K and investigations into the saturation density up to a pressure of 1 MPa, correlation equations have been set up which reproduce the measured values within the uncertainty of measurement.
引用
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页码:179 / 190
页数:12
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